First, we can ping hostname(ip_addr) to add mac/ip mapping into arp table
or use arp command to do so:
> arp -s hostname(ip_addr) MAC_addr
Second, look up arp table:
> arp -n (I recommend to use "-n" for avoiding DNS lookup. It is faster.)
Address HWtype HWaddress Flags Mask Iface
10.3.207.245 ether 20:aa:4b:a3:4c:b7 C eth4
or there is another way:
> ip ne
10.3.207.245 dev eth4 lladdr 20:aa:4b:a3:4c:b7 REACHABLE